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We have a fully-outfitted solid state chemistry lab used mainly for
the growth of high quality crystals. The crystal growth effort is
aimed at developing the high-quality samples required for
investigating the fundamental properties of high temperature
superconducting materials.
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We also have a film growth lab, focussed on the
production of films by laser ablation. The lab's main aim is
development of materials and processing suitable for electronic
applications of superconductors and is described in more detail
under Applied Research.
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At the present time, the main materials project
is the development of very high purity samples of YBCO grown in
homemade BaZrO3 crucibles. Recent thrusts include
manipulating the doping of these materials to the edge of where
they cease to be superconducting and a study of phases which
exhibit oxygen ordering. We are also continuing to study the
effects of various impurities such as Zn, Ni, and Ca on the
properties of single crystals of YBCO.
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Research in this area of materials involves
technical expertise in areas ranging over solid state chemistry,
physics, and ceramic engineering. The materials research drives a
wide range of technical projects such as Ruixing Liang's
development of the custom-made 3-zone furnace depicted here.
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One of our students, Darren Peets, has been
working on the growth of single-crystalline
Tl2Ba2CuO6+x (Tl-2201).
This compound is an intrinsically overdoped single-layer cuprate,
making it of great interest to the field. However, it has been
poorly studied due to issues arising from the extreme toxicity and
volatility of thallium oxide. These considerations make the
crystal growth process awkward and arduous.
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While we have succeeded in growing mm-sized
crystals of this compound, a great deal of work lies ahead. For
instance, the growth technique needs to be optimized and several
oxygen annealing issues are still being dealt with.
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